Pentanuclear tetra-decker luminescent lanthanide Schiff base complexes
نویسندگان
چکیده
منابع مشابه
Pentanuclear tetra-decker luminescent lanthanide Schiff base complexes.
Luminescent pentanuclear tetra-decker Ln(III) complexes [Eu5L4(OH)2(NO3)4(H2O)2].NO3.3H2O , [Nd5L4(OH)2(NO3)5MeOH].3MeOH.2H2O and [Eu5L4(CF3SO3)4(MeO)2(H2O)4].CF3SO3.H2O are formed from Ln(NO3)3.6H2O (Ln = Eu (1), Nd (2)) and Eu(CF3SO3)3, respectively (H2L = N,N'-bis(5-bromo-3-methoxysalicylidene)phenylene-1,2-diamine).
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The reliability of lanthanide luminescence measurements, by both flow cytometry and digital microscopy, would be enhanced by the availability of narrowband emitting, UV excited lanthanide calibration beads. 0.5-, 3-, and 5-microm beads containing a luminescent europium-complex are manufactured. The luminescence distribution of the 5-microm beads is measured with a time-delayed light-scatter-gat...
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The first two families of homodinuclear lanthanide(III) complexes, formulated as [(L(OEt))2Ln2(L1)] and [(LOEt)2Ln2(L2)] (Ln(3+) = Dy(3+), Tb(3+), Ho(3+), Gd(3+), and Y(3+); L1(4-) = 2,2',2'',2'''-[1,2,4,5-benzenetetrayltetrakis(nitrilomethylidyne)]tetrakisphenolate; L2(4-) = 2,2',2'',2'''-[[1,1'-biphenyl]-3,3',4,4'-tetrayltetrakis(nitrilomethylidyne)]tetrakis(4-chlorophenolate); L(OEt)(-) = (η...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2008
ISSN: 1477-9226,1477-9234
DOI: 10.1039/b801513a